Polyamide 610 injection molding GOST 10589 87. Basic grades of polyamides. A series of polyamides with various types of fillers


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STATE STANDARD OF THE USSR UNION

POLYAMIDE 610 INJECTION

2. Tensile strength, MPa (kgf/cm*)

3. Tensile yield strength, MPa (kgf/cm*)

4. Breaking stress at shear, MPa (kgf/cm*)

5. Tensile modulus of elasticity, MPa (kgf/cm2)

1.5-1.7- 10" (1.S-1.7. 10*)

6. Brinell hardness, MPa (kgf/mm*)

7. Elongation at break, not less

8. Coefficient of friction on steel

9. Heat resistance according to Vicat, ° C

10. Heat resistance according to Martens, ° C

11. Coefficient of linear expansion per G C in the temperature range 20-200 ° C

12. Maximum water absorption,%

13. Shrinkage during injection molding, %

On samples of various shapes

14. Specific surface electrical resistance (after staying in water at (20 ± 2) C for 24 hours), Ohm

5* 10‘* - 1* 10 13

15. Dielectric constant at 10 6 Hz

Continuation of the table. 3

Indicator name

Test method

17. Bending temperature under load at a stress of 1.80 MPa, 0 C

at a = 1.85 MPa (18.5 kgf/cm 2)

at O - 0.45 MPa (4.5 kgf/cm 2)

18. Impact strength, kJ/m 2 (kgf cm/cm 2), on notched samples at minus 65°C

1,96-3,92(2,0-4,0)

19. Charly impact strength, kJ/m 2 (kgf* cm/cm 2), on samples without a notch

20. Specific volume resistivity, Ohm * cm

21. Modulus of elasticity in bending, MPa

22. Softening temperature during bending, °C at a stress of 0.45 MPa

23. Thermal conductivity coefficient at a temperature of 20-150° C, W/ (m * K)

24. Oxygen index, %

Resistance to radiation exposure in percent

Table 4

Radiation dose, L^rad

Impact strength (notched samples)

Bending

voltage

Brinell hardness

Coefficients of retention of properties of PA 610 in the process of heat and humidity aging

Conditions of heat and humidity aging

Duration of aging, days

tensile yield strength

elongation at break

tensile strength

At a temperature

20°C humidity 80%

At a temperature

20°C humidity 98%

At a temperature

50°C humidity 80%

Notes: Rtek

\.K =

gi r K - property retention coefficient;

^tek ~ values ​​of indicators (tensile yield strength, elongation at break, tensile strength) under given aging conditions;

Likh “values ​​of indicators determined according to the relevant standards for the method of determining these indicators.

2. Test samples are manufactured in accordance with GOST 12019-66 and paragraphs. 3.2.1, 3,2.2, 3.2.3 of this standard.

Coefficients of retention of properties of PA 610 during exposure to elevated temperatures


Table 6


Property retention factor (K)

1 smpsrnturya

exposure, 0 C

11rODULZHI1SD6*

exposure duration, days

Tensile yield strength

Relative Strength Tensile-at-break elongation

Notes:

1. After exposure to elevated temperatures

before the test

samples are conditioned according to clause 3.2.3 of this standard.

2. Calculation of the coefficient of property retention (/O) is carried out according to the note to Table 5.


INFORMATION DATA 1. DEVELOPED AND INTRODUCED by the Ministry of Chemical Industry CONTRACTORS:

G.I. Faidel, Ph.D. tech. sciences; L.A. Nosova, Ph.D. tech. sciences; EL. Tatevosyan, Ph.D. tech. sciences; A.A. Lukor, Ph.D. chem. sciences; S.V. Khorev; T.A. Dmitrina

2. APPROVED AND ENTERED INTO EFFECT by Resolution of the USSR State Committee on Standards dated 09/02/87 No. 3448

4. REFERENCED REGULATIVE AND TECHNICAL DOCUMENTS

etc. "EVIL of this standard

10. Mountain resistance

clause 3.11 of this experience* dart

note 1 shall be stated in a new edition: “1. It is allowed in injection molded polyamide the presence of granules with a size of less than 2 mm (crumbs) and more than 5 to 8 mm, no more than 6% of the batch and a mass fraction of water no more than 0.5%";

The table should be supplemented with note - 6: “6. Determination of indicator 56 is mandatory until 01/01/94 only for a data set of at least 50 batches. The standard for indicator 5a is valid until 01/01/94.”

Clause 1.2.1. Replace the words: “Afraid of dampness” with “Keep away from moisture.” Clause 1.3.1. The first and second paragraphs shall be stated in a new edition: “Injection molded polyamide 610 is packaged in multilayer paper bags of the NM brand in accordance with GOST 2226-88 with a polyethylene liner - or in bags made of vinyl artificial leather with a polyethylene liner according to regulatory and technical documentation, as well as in multilayer paper bags bags of brands VM, VMP, PM, VMP according to GOST 2226-88.

(Continued on page 128)

The neck of the polyethylene liner, after filling with the material, is welded, the paper bag and the vinyl artificial leather bag are stitched by machine”;

last paragraph. Replace value: ±0.2 kg by ±3%; exclude the word: “soft”.

Clause 2 2. The second paragraph should be stated in a new edition: “Indicator 8

table 1 is determined for a batch of polyamide for electrical insulation purposes, indicators 4, 5, 7 are determined at least every tenth batch, indicator 6 - at least once a month, and indicators 9 and 10 - when the manufacturing technology changes."

Clause 3.6 after the word “metacresol” is added with the words: “or sulfuric acid”.

Clause 3.8. First paragraph. Replace the words: “at the speed of movement of the pendulum at the moment of impact (2.9±10%) m/s” with “at the nominal speed of movement of the pendulum at the moment of impact 2.9 m/s”;

second paragraph. Replace the words: “no more than 0.1 mm” with “no more than 0.2 mm”.

Section 3 should be supplemented with paragraphs - 3.10, 3.11: “3.10. I determine the oxygen index*? according to GOST 12.1.044-89 option A on samples of type 1, manufactured in accordance with clause 2 of table. 2.

3.11. Resistance to combustion is determined according to GOST 28157-89 (method B) on samples with a thickness of (4.0±0.5) mm and a width of (10.0±0.5) mm. Conditioning time - 88 hours.”

Clause 4.1. The second paragraph should be amended in a new edition: “It is allowed to enlarge cargo items into transport packages using fastening means in accordance with GOST 21650-76 to pallets in accordance with GOST 9557-87.”

Application. Table 3 should be presented in a new edition:

(Continued on page 129)

APPLICATION

Information

Reference indicators of injection molded polyamide 610

Table 3

Name of the company

Test method

1. Density, g/cm 3

2. Impact strength according to Chartzi on samples of type 3, kJ/m 2 (kgsХ X cm/cm 2), not less than:

with type A notch at temperature

without cut

3. Indentation hardness

ball pressure, MPa

4. Modulus of elasticity,

MPa (kgf/cm 2): when bending

1.610 a -1.7-Iu 3 (1.6-Iu 4 -1.7-10 4)

when stretched

1.5*10 3 -1.7-10 3 (1.5*10 4 - 1.7-10 4)

5. Strength during races

tension, MPa (kgf/cm 2) 6, Yield strength

in tension, MPa

7, Elongation at break, %,

8. Tensile strength

at shear, MPa (kgf/cm2)

9. Specific volume

resistance, Ohm cm, not less

(Continued on page 130)

Table 1

Indicator name

Test method

1. Appearance

Unpainted

Clause 3.3 of this standard

2. Mass fraction of granules measuring 2-5 mm in length and width, %, not less

Clause 3.3 of this standard

3. Mass fraction of water, %, no more

Clause 3.4 of this standard

4. Melting point, ° C, not less

5-10" g -1-10 18

11. Dielectric constant at hour-

tote Ш 6 Hz

12. Tangent of the dielectric loss angle at a frequency of 10 6 Hz, not

13. Bending temperature under load, °C, not less, at:

14. Temperature times

softening according to Yoika, °С

15. Heat resistance according to

Martens, °С

16. Tre coefficient

steel research

17. Average coefficient of linear thermal expansion per 1 °C in the temperature range

18. Thermal conductivity in the temperature range from

20 to 150 °C, W/m-K

19. Melt flow rate at a temperature of 235 ° C, strength 21,

19N (2.160 kg), g/10 min

20. Maximum water absorption, %, not more

21. Shrinkage,%

0.8-1.5 (IMS No. 6 1992)

610 decomposes releasing carbon monoxide, ammonia, and carbon dioxide.

The maximum permissible concentration of ammonia is 20 mg/m 1 2, the maximum permissible concentration of carbon monoxide is 20 mg/m 2.

1.1.3.4. Monitoring the state of the air environment - in accordance with GOST 12.1.005-76.

1.1.3.5. Molded polyamide 610 is processed in compliance with safety regulations in accordance with GOST 12.3, 030-83.

1.2. Marking

1.2.1. Transport marking - in accordance with GOST 14192-77 indicating the handling sign “Afraid of dampness” and the following details;

name of the manufacturer or its trademark;

product names;

batch numbers;

gross and net weights;

dates of manufacture;

symbols of this standard.

When packaging injection molded polyamide 610, a label is attached or glued to each bag in accordance with clause 1.2.1.

When packaging injection molded polyamide 610 in soft containers, transport markings are applied to the side surface of the container or accompanying documents are placed in a special pocket located on the inner surface of the container.

1.3. Package

1.3.1. Molded polyamide 610 must be packed in five or four or other paper bags of the GSh; BMP, 8MP brands and in accordance with GOST 2226-75 with a polyethylene liner according to the normative and technical documentation, or in shredded bags, or in bags made of vinyl artificial leather according to the normative and technical documentation with polyethylene liner.

The neck of the polyethylene liner, after filling with the material, is welded, and the neck of the paper, spreed and vinyl leatherette bag is stitched by machine.

The net weight of a packaging unit must be no more than 25 kg.

If there are crumbs in the batch, they must be packaged separately from the granules.

It is allowed to pack molded polyamide 610 in soft specialized containers for bulk products, soft specialized disposable containers of types MKR-1, OS or MKR-1, OM according to regulatory and technical documentation.

A soft specialized container of type MKR-1, OS is used only with a plastic liner bag.

Maximum deviation from the nominal weight is ± 0.2 kg when packed in bags, ± 3 kg when packed in soft containers.

the quality of homogeneous material of the same brand, obtained in one technological cycle and accompanied by one quality document.

The batch weight must be at least 500 kg.

The quality document indicates the following data: name of the manufacturer or its trademark; Product name; batch number; net weight;

quantity of packaging unit in a batch; test results; date of manufacture; designation of this standard.

2.2. For quality control, 10% of packaging units from a batch are randomly selected, but not less than three units. If the lot size is less than three units, samples are taken from each unit of packaging.

2.3; If unsatisfactory test results are obtained for at least one of the indicators, repeated tests are carried out on a double sample taken from the same batch.

The results of repeated tests apply to the entire batch. 3

3.2.3. Samples for testing according to indicators 6.7 table. 1 immediately after their manufacture (injection molding) they are placed in a plastic bag, the neck of which is sealed, and stored in an empty desiccator (moisture-proof container) at room temperature for at least 16 hours and no more than 10 days. The time from the moment the samples are removed from the bag (desiccator) until the end of the test should not exceed 40 minutes. If the seal is broken, drying is not allowed. New samples should be made. Test temperature (20 ± 2) °C.

3.2.4. Samples for testing according to indicator 8 of table. 1 before testing is conditioned according to GOST 6433.1-71. Samples are not normalized.

Conditioning and testing conditions for samples: (24 ± 1.2) h, (20 ± 2) ° C (liquid); M 15-35 ° C (liquid). Conditioning is carried out in distilled water. Before testing, the samples are removed from the water and dried with filter paper. The time from the moment the samples are removed from the water until the end of the tests should not exceed 40 minutes.

The test is carried out in transformer oil according to GOST 982-80.

3.3.Determination of appearance

3.3.1. The appearance of polyamide 610 is determined by comparing 100 g of the product isolated from an average sample with a control sample in the form of granules, approved in accordance with the established procedure.

3.3.2. The mass fraction of granules measuring 2-5 mm is determined as follows.

About 100.0 g of an average sample of injection molded polyamide 610 is weighed on a general purpose scale according to GOST 24104-80 of the 2nd accuracy class with a maximum weighing limit of 200 g or others having identical metrological characteristics, and placed on a sheet of graph paper. An arbitrary number of granules are sequentially separated, distributed in a single layer, and granules with a size of less than 2 and more than 5 mm are selected by visual inspection for 5 minutes. The remaining granules are weighed on scales of the same accuracy class.

The mass fraction of granules measuring 2-5 mm (A) - as a percentage is calculated using the formula

X - 100%,

where t j is the mass of the remaining granules, g;

t 2 - mass of sample taken for determination, g.

3.4. Determination of the mass fraction of water

3.4.1. The mass fraction of water is determined according to GOST 25055-87.

3.4.2. Determination of the mass fraction of water by drying method

3.4.2.1. Analysis tools

table 2

Processing parameters

Name

indicator

Sample dimensions, mm

injection pressure, MPa (kgf/cm2)

melt temperature,

mold temperature, 0 C

heating cylinder temperature,

holding time under pressure, s

cooling, with

1. Charpy impact strength

(120.0 ± 2.0) X (10 ± 0.5) X (4.0 ± 0.2)

Fused calcium chloride according to regulatory and technical documentation or technical calcium chloride according to GOST 450-77, pre-calcined.

3.4.2.2. Carrying out the test

Approximately 2,000-3,000 g of cast polyamide 610 is weighed by placing in a weighing cup, previously dried at a temperature of (125 ± 5) ° C for 30 minutes. The glass with the test sample is placed in a drying cabinet and dried at a temperature of (125 ± 5) °C for 4 hours, with the lid slightly opened.

The closed cup is cooled in a desiccator with calcined calcium chloride according to regulatory and technical documentation or another desiccant and weighed.

3.4.2.3. Processing the result

The mass fraction of water (Jfj) as a percentage is calculated using the formula:

where m is the mass of a sample of cast polyamide 610, g;

t \ t 4 - masses of the cup with injection molded polyamide 610 before and after drying, respectively, g.

The test result is taken as the arithmetic mean of the results of two determinations, the permissible discrepancy between which should not exceed 0.05%.

3.4.3. In case of disagreement, the mass fraction of water is determined according to GOST 25055-81.

3.5. The melting point is determined according to GOST 21553-76 (VA method). Pre-molded polyamide is crushed in a crusher or manually with a cutting tool and dried for 30-40 minutes at a temperature of 100-105°C.

The test result is taken as the arithmetic mean of the results of two parallel determinations, the discrepancy between which should not exceed 2°C.

3.6. The viscosity number is determined according to GOST 11034-82. Metacresol is used as a solvent. Preliminary extraction is not carried out.

3.7. Bending stress is determined according to GOST 4648-71 at

deflection equal to 1.5 sample thickness. Tests are carried out on five samples. Sample size (10.0±0.5) X (4.0±0.2) X (120±2.0) mm.

3.8. Charly impact strength is determined according to GOST 4647-80 on type 3 samples with a type A notch at the speed of the pendulum at the moment of impact (2.9 ± 10%) m/s.

An incision on the sample is made with a single-tooth cutter made from cutter 2254-0766 2 (GOST 2679-73) by removing all the teeth and sharpening one tooth. In this case, it is necessary to ensure the perpendicularity of the end and side edges, and the rounding radius between the end and side edges should be no more than 0.1 mm.

The rotational speed of the horizontal spindle is (26.7 ± 1.7) s" 1 or (1600 ± 100) rpm, feed speed 80-10 mm/min. Tests are carried out on five samples.

Control of the shape and size of the cut is carried out by monitoring the cutter tooth profile in accordance with GOST 4647-80.

3.9. Electrical strength is determined according to GOST 6433.3-71 on less than five samples in the form of disks with a diameter of (100 ± 1) mm, a thickness of (2.0 ± 0.2) mm at a frequency of 50 Hz and a smooth rise in voltage at a speed of 2-3 kV /c. Brass push electrodes with a diameter of 25 mm and a radius of curvature of 3 mm. The thickness of the sample is measured at five points evenly spaced on the surface of the sample using any measuring instrument with an error of no more than 0.02 mm.

4. TRANSPORTATION AND STORAGE

4.1. Molded polyamide 610 is transported by all types of transport in covered vehicles in accordance with the rules for the carriage of goods in force for this type of transport, and the technical conditions for loading and securing cargo.

Cargo packages are formed into transport packages in accordance with GOST 21929-76. The dimensions and weight of the package must comply with GOST 24597-81, fastening means - GOST 21650-76.

When transported by rail, injection molded polyamide 610 is transported in packages or carloads.

By road and air transport, injection molded polyamide 610 is transported in soft containers or in small shipments.

4.2. Molded polyamide 610 is stored in a closed, dry room. 4

determine the mass fraction of water (section 3.4.). If results are obtained above the norm established in table. 1, the material is dried, as indicated in paragraph 3.2.1, to a mass fraction of water of no more than 0.2%.

6. MANUFACTURER WARRANTY

6.1. The manufacturer guarantees compliance of injection molded polyamide 610 with the requirements of this standard, subject to the conditions of transportation, storage and operation established by the standard.

6.2. The guaranteed shelf life of injection molded polyamide 610 is one year from the date of its manufacture.

Molded polyamide 610 is accepted in batches. A batch is considered to be the number of

TEST METHODS

3.1. Spot samples are taken from bags with a scoop, and from containers with a probe in accordance with GOST 2517-85 from three levels along the height of the product/collected product, as indicated in clause 2.2. Point samples are combined together.

The resulting total sample is thoroughly mixed and the mass of the average sample is brought to at least 2 kg using the quartering method.

The selected average sample is placed in a clean, dry, tightly closed jar or plastic bag, the neck of which is sealed or tied. A label with the name of the product, batch number and sampling date is placed on the jar or placed inside the bag.

3.2. Tests of injection molded polyamide 610 according to indicators 6-8 tables. 1 is carried out on samples made by injection molding on injection molding machines with screw plasticization in compliance with the general requirements of GOST 12019-66. The surface of the samples selected for testing must be smooth, shiny, without “silver”, shells, blisters, sink marks, or burrs.

3.2.1. Before making samples, the product must be dried in a heating cabinet or in a vacuum cabinet at a temperature of 80-90 ° C to a mass fraction of water of no more than 0.2%.

3.2.2. The casting mode, shapes and dimensions of the samples are given in table. 2. To avoid destruction, the material should be in the heating cylinder of the injection molding machine for no more than 15 minutes.

DIRECTIONS FOR USE

5.1. Molded polyamide 610 is a hygroscopic material, therefore an increase in the mass fraction of water (more than 0.2%) during storage is not a reason for its rejection.

5.2. Before processing injection molded polyamide 610 into products in it

POLYAMIDE 610 INJECTION

TECHNICAL CONDITIONS GOST 10589-87

Official publication

USSR STATE COMMITTEE ON STANDARDS Moscow

UDC 678.673 *06.354 Pear L27

STATE STANDARD OF THE USSR UNION

POLYAMIDE 610 MOLDING Tvhyuteskm conditions

Molding polyamide 610 Specification

DeAstakya period from 01L7L8

Ngsoblvdepe stayadarta is pursued in mhoyau

This standard applies to lithium polyamide 610, which is a polycondensation product of the SG salt (salt of hexamethylene diamine and sebaic acid).

Molded polyamide 610 is intended for injection molding of various products for structural and electrical insulating purposes.

Products made from injection molded polyamide 610 can be used without reducing mechanical properties in the temperature range from minus 60 to plus 70°C, including electrical insulating products operated at low and medium frequencies.

For products that do not experience mechanical stress during operation, the upper temperature limit can be increased to plus 100 C.

Molded polyamide 610 is resistant to hydrocarbons, organic solvents, oils and alkalis. Molded polyamide 610 is resistant to solar radiation.

The technical level indicators established by this standard are provided for the highest quality category.

1. TECHNICAL REQUIREMENTS

1.1.Characteristics

1.1.1. Molded polyamide 610 must be manufactured in accordance with the requirements of this standard according to technological regulations approved in the prescribed manner.

1.1.2. Molded polyamide 610 must meet the requirements and standards specified in table. 1.

Forbid reprint

Iadmie ofmtsyavlmoe

© Standards Publishing House, 1987

S. 2 GOST 10589-87

Table I

Indicator name

Test method

1. Appearance

Unpainted

Clause 3.3 of this

standard

2. Mass fraction of granules

measuring 2-5 mm in length

Clause 3.3 of this

and width, %, less

standard

3. Mass fraction of iodine,

Clause 3.4 of this

%, no more

standard

4. Melting point.

* C, no less

of this standard

5. Viscosity number, cm’/g

of this standard

6. Bending stress

at a given deflection value.

MPa (kgf/cm 1), not less

of this standard

7. Charpy impact strength,

kJ/m’ (kg* cm/cm’),

of this standard

8. Electric strength.

kV/mm. less than

of this standard

Notes:

1. It is allowed to produce injection molded polyamide 610 > aile crumbs with a size of no more than S mm up to 5% of the batch weight.

2. The presence of oxidized particles is allowed in accordance with the control sample in the form of granules, approved in accordance with the established procedure.

3. The standard for indicator 8 is determined for batches intended for electrical insulation purposes.

4. Reference indicators of injection molded polyamide 610 are given in table. 3.4 applications.

5. Coefficients characterizing the preservation of properties during the aging process are given in table. 5.6 applications.

An example of a symbol for injection molded polyamide 610:

Polyamide 610 injection molding GOST 10589-87

1.1.3. Safety requirements

1.1.3.1. Molded polyamide 610 is non-toxic at temperatures up to 300° C and does not have a harmful effect on the human body.

1.1.3.2. During the processing of molded polyamide 610 by injection molding at a temperature of 260-270 ° C, decomposition and release of harmful substances does not occur.

1.1.3.3. At temperatures above 300° C in air, injection molded polyamide

GOST 10589 -87 S. 3

610 decomposes releasing carbon monoxide, ammonia, and carbon dioxide.

The maximum permissible concentration of ammonia is 20 mg/m 1, the maximum permissible concentration of carbon monoxide is 20 mg/m 3.

1.13.4. Monitoring the state of the air environment - in accordance with GOST 12.1.005-76.

1.1.3.5. Molded polyamide 610 is processed in compliance with safety regulations in accordance with GOST 12.3.030-83.

1.2. Marking

1.2.1. Transport marking - according to GOST 14192-77 indicating the handling sign “Afraid of dampness” and the following details,

name of the manufacturer or its trademark;

product names;

batch numbers;

gross and net weights;

dates of manufacture; ,

“notations of this standard.

When packing injection-molded polyamide 610, a label is attached to each npi bag in accordance with clause 1.2.1.

When packaging injection molded polyamide 610 in soft containers, transport markings are applied to the side surface of the container or accompanying documents are placed in a special pocket located on the inner surface of the container.

1.3. Package

1.3.1. Molded polyamide 610 must be packaged in five-four-layer paper bags of the PM, BMP, VMP brands and in accordance with GOST 2226-75 with a polyethylene liner according to the normative and technical documentation, or in spreed bags, or in bags made of vinyl artificial leather according to the normative and technical documentation with polyethylene liner.

After filling with macherial, the neck of the polyethylene liner is welded; the paper, spreed and vinyl leatherette bags are stitched by machine.

The net weight of a packaging unit must be no more than 25 kg.

If there are crumbs in the batch, they should be packaged separately from the granules.

It is allowed to pack molded polyamide 610 in soft specialized containers for bulk products, soft specialized disposable containers of types MKR-1, OS or MKP-I, OM according to regulatory and technical documentation.

A soft specialized container of type MKR-1, OS is used only with a plastic liner bag.

Maximum deviation from the nominal weight t 0.2 kg when packed in bags, t 3 kg when packed in soft containers.

Molded polyamide 610 is accepted in batches. A batch is considered to be the number of

S. 4 GOST 10689-87

the quality of homogeneous material of the same brand, obtained in one technological cycle and accompanied by one quality document.

The mass of the batch must have been at least 500 kg.

The quality document indicates the following data: name of the manufacturer or its trademark; Product name; batch number; net weight;

number of packaging units in a batch; test results; date of manufacture; designation of this standard.

2.2. For quality control, 10% of packaging units from a batch are randomly selected, but not less than three units. If the lot size is less than three units, samples are taken from each unit of packaging.

2.3. If unsatisfactory test results are obtained for at least one of the indicators, repeated tests are carried out on a double sample taken from the same batch.

The results of repeated tests apply to the entire batch.

3. TEST METHODS

3.1. Point samples are taken from bags with a scoop, and from containers with a probe in accordance with GOST 2517-85 from three levels along the height of the product/lobe, as indicated in clause 2.2. Point samples are combined together.

The resulting total sample is thoroughly mixed and the mass of the average sample is brought to at least 2 kg using the quartering method.

The selected average sample is placed in a clean, dry, tightly closed jar or plastic bag, the neck of which is sealed or tied. A label with the name of the product, batch number and sampling date is glued to the jar or placed inside the bag.

3.2. Tests of injection molded polyamide 610 according to indicators 6-8 tables. 1 is carried out on samples made by injection molding on injection molding machines with screw plasticization in compliance with the general requirements of GOST 12019-66. The surface of the samples selected for testing must be smooth, shiny, without “silver”, shells, blisters, sink marks, and burrs.

3.2.1. Before making samples, the product must be dried in a heating cabinet or in a vacuum cabinet at a temperature of 80-90°C to a mass fraction of water of no more than 0.2%.

3.2.2. Ligya mode, shapes and sizes of samples are given in table. 2. To avoid deterioration, the material should be in the heating cylinder of the injection molding machine for no more than 15 minutes.

GOST 10589-87 S. 5

3.2.3. Samples for testing according to indicators 6.7 table. 1 immediately after manufacturing (injection molding) is placed in a plastic bag, the neck of which is sealed, and stored in an empty desiccator (moisture-proof container) at room temperature for at least 16 hours and no more than 10 days. The time from the moment of removing samples of the package (dessiccator) to the end of the test should not exceed 40 minutes. If the seal is broken, drying is not allowed. New samples should be made. Test temperature (20 * 2)°C.

3.2.4. Samples for testing according to indicator 8 of table. I before testing is conditioned according to GOST 6433.1-71. Samples are not normalized.

Conditioning and testing conditions for samples: (24 ± 1.2) h, (20 ± 2) °C (liquid); M 15-35°C (liquid). Conditioning is carried out in distilled water. Before testing, the samples are removed from the water and dried with filter paper. The time from the moment the samples are removed from the water until the end of the tests should not exceed 40 minutes.

The test is carried out in transformer oil according to GOST 982-80.

3.3.0 appearance limit

3.3.1. The appearance of polyamide 610 is determined by comparing 100 g of the product isolated from an average sample with a control sample in 1nd granules, approved in the prescribed manner.

3.3.2. The mass fraction of granules measuring 2-5 mm is determined as follows.

About 100.0 g of an average sample of injection molded polyamide 610 is weighed on a general purpose scale in accordance with GOST 24104-80 of the 2nd accuracy class with a maximum weighing limit of 200 g or others having identical metrological characteristics, and placed on a sheet of graph paper. An arbitrary number of granules are sequentially separated, distributed in a single layer, and granules with a size of less than 2 and more than 5 mm are selected by visual inspection for 5 minutes. The remaining granules are weighed on scales of the same accuracy class.

The mass fraction of granules measuring 2-5 mm (DG) as a percentage is calculated using the formula

where/i | - mass of remaining granules, g;

t g - mass of the sample taken for determination, g.

3.4. Determination of the mass fraction of water

3.4.1. The mass fraction of water is determined according to GOST 25055-87.

3.4.2. Determination of the mass fraction of water by drying method

3.4.2.1. Analysis tools

table 2

Processing parameters

Named**

indicator

sample, mm

injection rate, MPa (kg/cm 1)

t ampere of melt atmosphere,

tamaeratu-ra yak pe-

howl form. in C

heating cylinder temperature,

time a ml er f km iodine pressure, s

cooling time, s

1. Charly impact strength

3.9. Electrical strength is determined according to GOST 6433.3-71 on at least five samples in the form of disks with a diameter of (100 * 1) mm, a thickness of (2.0 * 0.2) mm at a frequency of 50 Hz and a smooth rise in voltage at a speed of 2-3 kV /With. Brass push electrodes with a diameter of 25 mm and a radius of curvature of 3 mm. The thickness of the sample is measured at five points evenly spaced on the surface of the sample using any measuring instrument with an error of no more than 0.02 mm.

4. TRANSPORTATION AND STORAGE

4.1. Molded polyamide 610 is transported by all types of transport in covered vehicles in accordance with the rules for the transportation of goods in force for this type of transport, and the technical conditions for loading and securing cargo.

Cargo packages are formed into transport packages in accordance with GOST 21929-76. The dimensions and weight of the package must comply with GOST 24597-81, fastening means - GOST 21650-76.

When transported by rail, injection-molded polyamide 610 is transported in packages or by carload.

By road and air transport, injection molded polyamide 610 is transported in soft containers or in small shipments.

4.2. Molded polyamide 610 is stored in a closed, dry room.

5. INSTRUCTIONS FOR USE

5.1. Molded polyamide 610 is a hygroscopic material, therefore an increase in the mass fraction of water (more than 0.2%) during storage is not a reason for its rejection.

5.2. Before processing injection molded polyamide 610 into products in it

GOST 10589 -L7 s. 9

determine the mass fraction of water (section 3.4.). If results are obtained above the norm established in table. 1. the material is dried as indicated

in clause 3.2.1, up to a mass fraction of water of no more than 0.2%.

6. MANUFACTURER WARRANTY

6.1. The manufacturer guarantees compliance of injection molded polyamide 610 with the requirements of this standard, subject to the conditions of transportation, storage and operation established by the standard.

6.2. The guaranteed shelf life of injection molded polyamide 610 is one year from the date of its manufacture.

S. 10 GOST 10589 -*7

APPLICATION

Information

REFERENCE INDICATORS OF MOLDING POLYAMIDE 610

Table 3

Nshmsyuinhe indicator

I will test the method*

1. Density, g/cm*

2. Tensile strength, MPa (kg/cm*)

3. Current™ tensile limit. MP" (kgf/cm*)

4. Breaking stress at shear, MPa (kgf/cm*)

5. Tensile modulus of elasticity, MPa (kgf/cm*)

1,5-1,7- 10" (14-1,7 10->

6. Hardness in Brinell, MPa (kgf/mm 1)

According to GOST 4670-77

7. Relative elongation or rupture. %, not meies

8. Coefficient of friction on steel

9. Heat resistance according to Vika, C

According to GOST 15065 69

10. Heat resistance according to Martens, * C

11. Coefficient of linear expansion by 1* C in the temperature range 20-200“C

12. Maximum water absorption, %

13. Shrinkage or casting by squeezing, %

On samples of various shapes

14. Udelamos surface zyectric resistance (after staying in water at (20 ± 2) C for 24 hours), Ohm

5. Dielectric constant at 10 4 Hz

GOST 10589 ^87 C 11

Table continued 3

Indicator name

I'll test it!*

17. Bending temperature under load at a stress of 1.80 MPa. 9 C

at o = I.8S MPa (18.5 kgf/cm") at 0 = 0.45 MPa (4.5 kgf/cm 1)

18. V lari al viscosity, kJ/m* (kg cm/cm’), on images with a notch at minus 65°C

19. Impact strength according to Charpy, kJ/m* (kg-cm/cm’), on images From the cut

20. Specific volume resistivity. Ohm cm

21. Modulus of elasticity in bending. MPa

22. Temperature of softening during bending. "C at stress 0.45 MPa 0.8 MPa 4.9 MPa

2). Heat transfer coefficient at a temperature of 20-150* C. W/(m K)

24. Oxygen index, %

C 12 GOST 10319-87

Resistance to dsLstyuo radioact of any irradiation and about u w tal

GOST 10589-87 S. 13

Characteristics of properties of PA 610 in the process* of moisture aging

Duration of aging, days

bone structure

hid fluidity when stretching them

relative elongation at break

when stretched

At a temperature

20* C humidity 80%

At a temperature

20°C humidity 98%

At a temperature

30* C humidity 80%

Notes:

where* K is the property retention coefficient;

^tek - zhacheknya pochat*tel* (limit* of yield of ora p*styazheikn, relative elongation at break, tensile strength) under given aging conditions;

L(C x - ZMA"KNHYA indicators, determined according to the relevant standards for the method for determining these indicators 2. Test samples are manufactured in accordance with GOST 12019-66 and clauses 3.2.1, 3.2.2, 3.2.3 of this standard.

S. 14 GOST 10589-87

Table 6

Coefficients of retention of properties of PA 610 ■ during exposure to high temperatures

Property retention coefficient (/G)

Exposure temperature* C

11roaolyao «teyaa-nosta impact, eut

Tensile yield strength

Elongation at break

Tensile strength

1. After exposure to elevated temperatures before testing

samples are conditioned according to clause 3.2.) of this standard.

2. Calculation of the property retention coefficient (U) is carried out according to the note to Table 5.

GOST 10589-87 S. 15

INFORMATION DATA

1. DEVELOPED AND INTRODUCED by the Ministry of Chemical Industry PERFORMERS:

G.I. Fschidel, Ph.D. tech. sciences; L.A. Nosova, cadet tech. sciences; EL. Tatevos*i, Ph.D. tech. sciences; A.A. Lukor, Ph.D. chem. sciences; S.V. Khorem; T.A. Dmntriaa

2. APPROVED AND ENTERED INTO EFFECT by Resolution of the USSR State Committee on Standards dated 09/02/87 N* 3448

3. INSTEAD GOST 10589-73.

4. REFERENCED REGULATORY TECHNICAL DOCUMENTS

GOST 450 -77

GOST 2226-75

GOST 2517-85

g OST 6433.3-71

GOST 11034 -82

GOST 21S53-76

GOST 21929-76

GOST 24104 -80

GOST 25055-81

GOST 25336-82

Group J127

Change /6 ! GOST 10589-87 Molded polyamide 610. Technical conventions

Approved and put into effect by the Decree of the USSR State Committee for Product Quality Management and Standards dated 20.0S.91.4 713

Date of introduction 01.11.91

Introductory part. Delete the last paragraph;

add a paragraph. “The requirements of this standard are mandatory*

Clause 1.1.2. Table |. Note 3 excluded..

Add paragraph 2.2: “Indicator 8 of table. I is determined for electronic insulation desks, indicators 4. 5, 7 are determined at least every tenth batch, and 6 - at least once per month*.

(IUS Nt 8 1991)

Change >* 2 GOST 10689-87 Molded polyamyl 610. Specifications

Approved and put into effect by Resolution of the State Standard of Russia dated March 27, 1992 J* 281

Date of introduction 01/91/9S

Introductory part. The last paragraph after the word “grnbostoek” should be supplemented with the words: “and stoek”;

indicator 5 should be stated in a new version; supplement the table with indicators-9, 10:

note 1 shall be stated in a new edition: “1. It is allowed in injection molded polyamide the presence of granules with a size of less than 2 mm (crumbs) and more than 5 to 8 mm and more than 6% of the batch and a mass fraction of the hearth of no more than 0.5 H>";

The table should be supplemented with note - 6: “6. Determination of the indicator 50 is mandatory until 01/01/94 only for a data set of at least 50 batches. The standard for indicator 5a is valid until 01/01/94.”

Clause 1.2.1. Replace the words: “Afraid of dampness” with “Keep away from moisture” Clause 1.3.1. The first and second paragraphs shall be stated in a new edition: “Injection molded polyamide 610 is packaged in yao-layer paper bags of the NM brand according to GOST 2226 - 88 with a polyethylene liner, or in vinyl plastic bags with a polyethylene liner according to the normative and technical documentation, as well as in multi-layer paper bags bags of VM, BMP brands. P."\. VMP io GOST 2226 -A8.

(Continuation of changes to GOST 10589-87)

After filling with the material, the neck of the polyethylene liner is welded. a paper bag and a vinply leather bag are stitched by machine;

last paragraph. Note value: ±0.2 kg at ±3%; exclude the word: “soft”.

Clause 2.2. The second paragraph should be stated in a new edition: “Indicator 8

Table 1 is determined for a batch of polyamide for electrical insulation purposes, indicators 4. 5, 7 are determined at least every tenth batch, indicator 6 - at least once a month, and indicators 9 and 10 - when the manufacturing technology changes."

Clause 3.6 after the word “metacresol” is added with the words: “or sulfuric acid”.

Clause 3.8. First paragraph. Replace the words: “at the speed of movement of the pendulum at the moment of impact (2.9±10%) m/s* with “at the nominal speed of movement of the pendulum at the moment of impact 2.9 m/s”;

second paragraph. Replace the words: “with more than 0.1 mm” with “no more than 0.2 mm”.

Section 3 should be supplemented with clauses 3.10, 3.11: “3.10. The oxygen index is determined according to GOST 12.1 0+4-89 option A on samples of type!. manufactured according to clause 2 of table. 2.

311. Burning resistance is determined according to GOST 28157 - 89 (method B) on samples with a thickness of (4.0 ± 0) mm and a width of (10.0 ± 0.5) mm. Conditioning time - 88 hours.”

Clause 4.1 The second paragraph should be stated in a new edition: “It is allowed to enlarge cargo items into transport packages using fastening means in accordance with GOST 21650 - 76 and pallets in accordance with GOST 9557-87.”

Application. Table 3 should be presented in a new edition:

(Continuation of changes to GOST 10569 -$7) APPENDIX Reference

Reference indicators of injection molded polyamide 610

Continued tobh >

Nmmsno"*yave po"dshi"

Mtroa am*

10. Specific over

GOST 6433 2-71

resistance resistance

(after staying in

de at temperature

(20±2) e C for 24 hours). Ohm

11. Dielectric

GOST 22372--77

permeability at hour

tote 10* Gi

12. Tangent of angle di

GOST 22372 -77

electrical losses

in the temperature range

GOST 23630 2-79

18. Thermal conductivity in

temperature range from

20 to 150 *C. W/m K

GOST 11645 - 73

19. Current indicator

honor melt at the same time

temperature 235 *C, less than 21, 19 N (2.160 kg), g/10 min

GOST 4660-80

20. Water absorption

maximum. %, sky

21. Shrinkage,%

(IUS -** 6 1992)

Reazhtor N.P. Shchukine Tekhshmsskiy editor O.N. Nikitina Proofreader V.I. Varents

Saaio" and "A. 09.22.87 Mean, to paa. 10/26/87 1.0 el. psch. I. 1.13 el. cr.-ott. 0.90 gch.-sha-"i. Tkr. 8000 Umi S kop.

Orvaia "Badge of Honor" Imitaistao standards. 123(40, Moek "a. GSP, Novolresnamsky par.. 3 Nabraio a Publishing house staashartov ia NPU Type. "Moscow ptaapgak". Moscow. Lyalii per.. 6. Zak. 6"?i

This material is a synthetic polymer with excellent physical and chemical properties. Comparing this brand of polyamide with others, the following distinctive properties can be identified:

  • – low moisture absorption coefficient;
  • – high electrical insulating properties;
  • – excellent dimensional stability of the material;
  • – low susceptibility to temperature deformation;
  • – high antifriction properties;
  • – high oil? and gasoline resistance.

Polyamide conforms to the chemical formula ([-NH-(CH2)6-NH-CO-(CH2)8-CO-]n).

Liteva polyamide 610 Intended for the manufacture of injection molding of various products for structural and electrical insulating purposes.

Molded polyamide products PA 610 can be operated without reducing mechanical properties in the temperature range from minus 60 to plus 70 degrees Celsius, including electrical insulating products operated at low and medium frequencies.

Glass-filled polyamide PA 610 has a number of improved properties. Its chemical inertness to many oils and alcohols, as well as its elasticity and elasticity at low temperatures, makes it possible to produce some of the highest quality parts from it. Glass-filled polyamides are characterized by increased strength and resistance to impact loads. Glass-filled polyamides are also characterized by good dielectric properties. Glass-filled polyamide is used to make parts of precision instruments, housings of power tools, such as drills, casings of small-sized pumps, cam disks, bearing cages, needle roller bearings, load-bearing parts of transformers, etc.

Soap filled polyamide PA 610 has increased anti-friction and electrical insulating properties. Compared to glass-filled polyamide, soap-filled polyamide has a higher impact strength, this is due to the low adhesion of glass fiber. Soap filled polyamide 610 has increased dimensional stability.

Graphite-filled polyamide PA 610 has even higher anti-friction properties.

Properties of Polyamide 610 Molded (GOST 10589-87)

Index Meaning
Appearance Uncolored granules
Density, g/cm 3 1,09 - 1,11
Mass fraction of granules measuring 2? 5 mm
in length and width,%, not less than:
95
Mass fraction of water, %, no more 0,2
Melting temperature °C, not less 215
Polyamide solution viscosity number
in metacresol, cm 3 /g
130 - 190
Polyamide solution viscosity number
sulfuric acid, cm 3 /g
103 - 170
Bending stress at a given
size, MPa (kgf/cm2), not less
44,1 (450)
Charpy impact strength, kJ/m?
(kgf cm/cm 2), not less
4,9 (5)
Tensile strength, MPa
(kgf/cm 2)
50 - 60 (500 - 600) 50 - 60 (500 - 600)
Tensile yield strength,
MPa (kgf/cm 2)
70 - 90 (700 - 900)
Breaking stress at shear,
MPa (kgf/cm 2)
40 - 50 (400 - 500)
Brinell hardness, MPa (kgf/mm 2) 100 - 150 (10 - 15)
Elongation at break,
% no less
100
Friction coefficient for steel 0,26 - 0,32
Water absorption max.,% 3,3
Shrinkage during injection molding, % 0,8 - 1,5
Electric strength, kV/mm,
no less
20
Oxygen index, % 24 - 25
Fire resistance

Polyamide 610.

Polyamide 610 is a polycondensation product of SG salt. Molded polyamide 610 is intended for injection molding of various products for structural and electrical insulating purposes.

Products made from injection molded polyamide 610 can be used without reducing mechanical properties in the temperature range from minus 60 to plus 70°C, including electrical insulating products operated at low and medium frequencies.

Technical characteristics of polyamide PA 610 L. GOST 10589-87

Number

Indicator name Meaning
1 Appearance Unpainted granules
2 Mass fraction of granules measuring 2-5 mm in length and width,%, not less 95
3 Mass fraction of water, %, no more 0,5
4 Melting temperature °C, not less 215
5 Polyamide solution viscosity number, cm3/ga) in metacresolb) in sulfuric acid 130-190 103-170
6 Bending stress at a given value, MPa (kgf/cm2), not less 44,1 (450)
7 Charpy impact strength (kJ/cm2), not less 4,9 (5)
8 Electric strength,% 20
9 Oxygen index, % 24-25
10 Fire resistance PV-2

For products that do not experience mechanical stress during operation, the upper temperature limit can be increased to plus 100°C.

Molded polyamide 610 is resistant to hydrocarbons, organic solvents, oils and alkalis. Molded polyamide 610 is resistant to solar radiation.

Polyamide copolymers.

One of the common methods for modifying polyamides is the synthesis of copolymers. Usually, for this purpose, a joint polycondensation of caprolactam, AG salt, and dodecalactam, taken in various ratios, is carried out.

The most important are:
1) Polyamide AK 80/20.
2) Polyamide PA 6/66-3, PA 6/66-4.
3) Polyamide PA 12/6/66.

Polyamide copolymer AK 80/20.

Molding copolymer of polyamide AK 80/20 is intended for the manufacture by injection molding of various products for structural purposes used in mechanical engineering, electrical industry, instrument making, etc. The temperature range of operation of products is from minus 50 to plus 70 degrees Celsius. Polyamide copolymer is resistant to hydrocarbons, organic solvents, oils, diluted and concentrated alkali solutions. It dissolves in concentrated mineral acids, formic and acetic acids, and in phenols.

Molded polyamide copolymers

Molded polyamide copolymers are intended for the production of injection molded various products for structural purposes, used in mechanical engineering, electrical industry, instrument making and other sectors of the national economy as substitutes for non-ferrous metals.

The operating temperature range for products made from injection molded polyamide copolymers is from minus 50 to plus 70°C. Molded polyamide copolymers are resistant to hydrocarbons, organic solvents, oils, diluted and concentrated alkali solutions. They dissolve in concentrated mineral acids, formic and acetic acid, and in phenols.

Physico-mechanical properties of injection molded polyamide copolymers

Indicator name

Standard for the brand
AK 93/70 AK 80/20
1. Density, g/cm 3 1,14 1,13
2. Tensile strength MPa (kgf/cm2) 58,8-68,6
(600-700)
58,8-68,6 (600-700)
3. Breaking stress during compression, MPa. (kgf/cm 2) 98,0-117,6 (1000-1200) 68,6-38,2 (700-900)
4. Breaking stress at shear, MPa (kgf/cm2) 19,5-58,8
(550-600)
49,5-58,8 (550-600)
5. Brinell hardness, MPa (kgf/cm2) 98,0-117,6 (1000-1200) 98,0-117,6 (1000-1200)
6. Elongation at break, % 80-100 200-300
7. Coefficient of friction on steel 0,24-0,25 0,22-0,23
8. Water absorption,%:
in 24 hours
maximum
2,1-2.2
9,0
2,5-2,6
10,0-11,0
9. Shrinkage,% 1,4-1,8 1,4-1,8
10. Impact strength of the sample without a notch, kJ/m 2 (kgf cm/cm 2):
at 0°C
at minus 20°C
at minus 50°C
102,9-107,8
(105-110)
98,0-107,8
(100-110)
83,3-98,0
(85-100)
91,1-98,0
(93-100)
107,8-112,7
(110-115)
98,0-107,8
(100-110)

Polyamide grades in the Simplex assortment

Polyamide (PA, PA) domestic including brands PA 6 210 and PA 6 210/310

Polyamide 6 210/310
(PA 6-210/310)

Designed for the production of products used in mechanical engineering, automotive industry, etc.

Polyamide 6 210 KS
(PA 6 210 KS)

Polyamide 6 210 filled with short glass.

Brand for casting and extrusion. Contains 30% fine fiberglass. For products of structural, electrical and general technical purposes

Polyamide 66 KS
(PA 66 KS)

Polyamide 66 filled with short glass.

Designed for the manufacture of parts operating under load; body parts; parts subject to transverse bending

Polyamide 66 injection molded
(PA 66 L)

Molded polyamide.

Designed for the manufacture of injection molded parts.

Polyamide 610 injection molded
(PA 610 L)

Molded polyamide, unfilled.

Designed for the production of technical parts of complex configuration, low-flammability, not allowed for contact with food products

Polyamide 610 LSV 30
(PA 610 LSV 30)

Glass filled polyamide.

Tough, scratch-resistant, resistant to acids, alkalis, oils. Used in automotive and mechanical engineering.

Polyamide 610-LT-20
(PA 610 LT-20)

Talcon-filled polyamide, elastic

Imported PA
(produced by Rhodia, France)

Oromid (Oromid)

A series of filled and unfilled polyamides, analogs of PA 66 and PA 66 with 30% glass filling.

High strength and wear resistant. They are used in the automotive industry, in the manufacture of household appliances, electrical equipment, parts operating under increased mechanical loads, etc.

Technyl (Teknil)

A series of polyamides with various types of fillers.

Tough and resistant to high temperatures. Processed by casting and extrusion. They are used for the manufacture of car parts, as well as dowels, clamps, clamps, coils, contact blocks, washing machine motors, etc.

Technyl Star Star)

A series of polyamides with improved flow properties, extremely high rigidity and dimensional stability.

Gives the product improved surface quality. They are used for the manufacture of electromechanical parts, used in the automotive industry, as well as in the production of consumer goods, household appliances, etc.

Technyl Star range

Volgamid®

Polyamide-6 obtained through the polymerization reaction of caprolactam followed by granulation. TU 2224-038-00205311-08 (with notices No. 1, 2) According to the main parameters and characteristics, polyamide-6 Volgamid ® fully complies with polyamide PA6-210/310 and 210-311 OST 6-06-S9-93

KuibyshevAzot produces Polyamide-6 in accordance with the following specifications:

  • Volgamid 25
  • Volgamid 24
  • Volgamid 24 SD
  • Volgamid 27
  • Volgamid 34
  • Volgamid F (food grade)

Primary granulated polyamide.

Designed for the production of a wide range of products: polyamide threads for technical purposes, composite materials with various properties (impact-resistant, frost-resistant, water-resistant, fire-resistant), textile fibers, polymer films.

Helpful information

Properties of polyamide:
Polyamide (PA) is a high molecular weight polymer containing an amide group. Combines hardness, rigidity, high mechanical strength, low density, good antifriction and dielectric properties. PA is resistant to oils, alkalis, solvents, gasoline. Parts made of polyamide can withstand loads close to those characteristic of non-ferrous metals and alloys. Polyamide has a low coefficient of friction, but high wear resistance and load-bearing capacity. PA is easy to paint and has good bonding properties.